The file that controls the mapping from file extension to mime type is /usr/local/apache/conf/mime.types

The files in /usr/local/apache/conf are under cvs in the apache repository.

cvs -d /home/cvsgigascale co apache
edited apache/conf/mime.types
cvs commit -m "Added pot extension for ppt files" apache/conf/mime.types                                            

Update the master version:

su - www
cd /usr/local/apache/conf
cvs update

Became root and restarted the server with

/etc/init.d/apache* stop
/etc/init.d/apache* start
See also Restarting the website